Year-wise listing of Publications:

2002

• Aromi, G., Bhaduri, S., Artus, P., Huffman, J. C., Hendrickson, D. N. and Christou, G. (2002). "A tetranuclear manganese carboxylate cluster with bis(2-pyridyl)amine ligation: [Mn4O2(O2CEt)7(bpya)2](ClO4)." Polyhedron 21(18): 1779-1786.
• Caulton, K. G., Ferrando-Miguel, G., Coalter, J. N., III, Gerard, H., Huffman, J. C. and Eisenstein, O. (2002). "Geminal dehydrogenation of ether and amine C(sp3)H2 groups by electron-rich Ru(II) and Os." Abstracts of Papers, 223rd ACS National Meeting, Orlando, FL, United States, April 7-11, 2002: INOR-002.
• Caulton, K. G., Ozerov, O. V., Watson, L., Huffman, J. C. and Pink, M. (2002). "Transformations of alkenes and alkanes by amido rhenium polyhydrides." Abstracts of Papers, 224th ACS National Meeting, Boston, MA, United States, August 18-22, 2002: INOR-554.
• Caulton, K. G., Ozerov, O. V., Watson, L. A., Huffman, J. C. and Pink, M. (2002). "Amide promoted reactivity of rhenium polyhydrides." Abstracts of Papers, 223rd ACS National Meeting, Orlando, FL, United States, April 7-11, 2002: INOR-356.
• Ho, V. M., Watson, L. A., Huffman, J. C. and Caulton, K. G. (2002). "Double C(sp3) dehydrogenation as a route to coordinated Arduengo carbenes: Experiment and computation on comparative .pi.-acidity." Abstracts of Papers, 223rd ACS National Meeting, Orlando, FL, United States, April 7-11, 2002: CHED-514.
• Kraft, B. J., Eppley, H. J., Huffman, J. C. and Zaleski, J. M. (2002). "Cu(II)-Mediated Intramolecular Carbene Cation Radical Formation: Relevance to Unimolecular Metal-Ligand Radical Intermediates." Journal of the American Chemical Society 124(2): 272-280.
• Sanudo, E. C., Grillo, V. A., Knapp, M. J., Bollinger, J. C., Huffman, J. C., Hendrickson, D. N. and Christou, G. (2002). "Tetranuclear Manganese Complexes with Dimer-of-Dimer and Ladder Structures from the Use of a Bis-Bipyridyl Ligand." Inorganic Chemistry 41(9): 2441-2450.
• Vedernikov, A. N., Caulton, K. G. and Huffman, J. C. (2002). "Alkane and arene functionalization in Pt-pyridinophane systems." Abstracts of Papers, 224th ACS National Meeting, Boston, MA, United States, August 18-22, 2002: INOR-562.
• Vedernikov, A. N., Caulton, K. G., Huffman, J. C. and Pink, M. (2002). "Room temperature C-H bond activation with PtMe2H(L)+ [L = [2,1,1]-(2,6)-pyridinophane]." Abstracts of Papers, 223rd ACS National Meeting, Orlando, FL, United States, April 7-11, 2002: INOR-351.
• Vedernikov, A. N., Wu, P., Huffman, J. C. and Caulton, K. G. (2002). "Cu(I) and Cu(II) complexes of a pyridine-based pincer ligand." Inorganica Chimica Acta 330: 103-110.

2001

• Antelmann, B., Chisholm, M. H., Iyer, S. S., Huffman, J. C., Navarro-Llobet, D., Pagel, M., Simonsick, W. J. and Zhong, W. (2001). "Molecular Design of Single Site Catalyst Precursors for the Ring-Opening Polymerization of Cyclic Ethers and Esters. 2.1 Can Ring-Opening Polymerization of Propylene Oxide Occur by a Cis-Migratory Mechanism?" Macromolecules 34(10): 3159-3175.
• Boskovic, C., Pink, M., Huffman, J. C., Hendrickson, D. N. and Christou, G. (2001). "Single-molecule magnets: ligand induced core distortion and multiple Jahn-Teller isomerism in [Mn12O12(O2CMe)8(O2PPh2)8(H2O)4]." Los Alamos Natl. Lab., Prepr. Arch., Condens. Matter: No pp. given, arXiv:cond-mat/0109533.
• Boskovic, C., Pink, M., Huffman, J. C., Hendrickson, D. N. and Christou, G. (2001). "Single-Molecule Magnets: Ligand-Induced Core Distortion and Multiple Jahn-Teller Isomerism in [Mn12O12(O2CMe)8(O2PPh2)8(H2O)4]." J. Am. Chem. Soc. 123(40): 9914-9915.
• Canada-Vilalta, C., Huffman, J. C. and Christou, G. (2001). "Preparation, crystal structure and chelate substitution reactions of [Mn4O2(O2CPh)6(dpm)2] (dpm = the anion of dipivaloylmethane)." Polyhedron 20(15-16): 1785-1793.
• Canada-Vilalta, C., Huffman, J. C., Streib, W. E., Davidson, E. R. and Christou, G. (2001). "Use of the dicarboxylate ligand m-phenylenedipropionate for the synthesis of new Mn/O clusters. Synthesis, characterization and magnetic properties." Polyhedron 20(11-14): 1375-1380.
• Caulton, K. G., Ozerov, O. V., Gerard, H., Watson, L. A., Patel, C. G. and Huffman, J. C. (2001). "Synthesis, reactivity, and structure of rhenium comlexes supported by pincer type diphosphinoamido ligands." Abstracts of Papers, 222nd ACS National Meeting, Chicago, IL, United States, August 26-30, 2001: INOR-229.
• Chandra, T., Huffman, J. C. and Zaleski, J. M. (2001). "A novel metalloenediyne coordination polymer: serpentine structure of [Cu(OAc)4(daed)]n." Inorg. Chem. Commun. 4(8): 434-436.
• Chisholm, M. H., Davidson, E. R., Huffman, J. C. and Quinlan, K. B. (2001). "A Comparison of the Influences of Alkoxide and Thiolate Ligands on the Electronic Structure and Reactivity of Molybdenum(3+) and Tungsten(3+) Complexes. Preparation and Structures of M2(OtBu)2(StBu)4, [Mo(StBu)3((NO)]2, and W(StBu)3(NO)(py)." J. Am. Chem. Soc. 123(39): 9652-9664.
• Coalter, J. N., III, Huffman, J. C. and Caulton, K. G. (2001). "Carbene transposition involving double dehydrogenation of an sp3 carbon." Chem. Commun. (Cambridge, U. K.)(13): 1158-1159.
• Ferrando, G., Gerard, H., Spivak, G. J., Coalter, J. N., III, Huffman, J. C., Eisenstein, O. and Caulton, K. G. (2001). "Facile C(sp2)/OR Bond Cleavage by Ru or Os." Inorg. Chem. 40(26): 6610-6621.
• Marchenko, A. V., Huffman, J. C., Valerga, P., Jimenez Tenorio, M., Puerta, M. C. and Caulton, K. G. (2001). "Effect of Lewis Acidity on the Synthesis of RuHCl(CO)(phosphine)2: Subtle Influence of Steric and Electronic Effects among PiPr3, PiPr2(3,5-(CF3)2C6H3), and PiPr2Me." Inorg. Chem. 40(25): 6444-6450.
• Moser, W. H., Sun, L. and Huffman, J. C. (2001). "Synthesis and Reactivity of Silyl Vinylketenes: A Formal Interrupted Doetz Benzannulation with Unexpected Silyl Migration." Organic Letters 3(21): 3389-3391.
• Sanudo, E. C., Grillo, V. A., Yoo, J., Huffman, J. C., Bollinger, J. C., Hendrickson, D. N. and Christou, G. (2001). "Synthesis, structural characterization and magnetic properties of mixed-valent bis-bipyridine manganese carboxylate clusters." Polyhedron 20(11-14): 1269-1272.
• Schmitt, E. W., Huffman, J. C. and Zaleski, J. M. (2001). "Thermal reactivities of isostructural d10 metalloenediynes: metal-dependent Bergman cyclization." Chem. Commun. (Cambridge)(2): 167-168.
• Soler, M., Artus, P., Folting, K., Huffman, J. C., Hendrickson, D. N. and Christou, G. (2001). "Single-molecule magnets: preparation and properties of mixed-carboxylate complexes [Mn12O12(O2CR)8(O2CR')8(H2O)4]." Los Alamos Natl. Lab., Prepr. Arch., Condens. Matter: 1-12, arXiv:cond-mat/0109438.
• Soler, M., Artus, P., Folting, K., Huffman, J. C., Hendrickson, D. N. and Christou, G. (2001). "Single-Molecule Magnets: Preparation and Properties of Mixed-Carboxylate Complexes [Mn12O12(O2CR)8(O2CR')8(H2O)4]." Inorg. Chem. 40(19): 4902-4912.
• Soler, M., Chandra, S. K., Ruiz, D., Huffman, J. C., Hendrickson, D. N. and Christou, G. (2001). "A third isolated oxidation state for the family of [Mn12O12(O2CR)16(H2O)4] compounds. Synthesis, characterization and single-molecule magnetism properties of (PPh4)2[Mn12O12(O2CR)16(H2O)x] (x = 3 or 4)." Polyhedron 20(11-14): 1279-1283.

2000

• Brechin, E. K., Knapp, M. J., Huffman, J. C., Hendrickson, D. N. and Christou, G. (2000). "New hexanuclear and octanuclear iron(III) oxide clusters: octahedral [Fe6O2]14+ species and core isomerism in [Fe8O4]16+ complexes." Inorg. Chim. Acta 297(1-2): 389-399.
• Chisholm, M. H., Click, D. R. and Huffman, J. C. (2000). "Octakis(trimethylsilylmethyl)dioxotetramolybdenum. A novel tetranuclear compound with two localized metal-metal triple bonds." J. Organomet. Chem. 614-615: 238-242.
• Chisholm, M. H., Eilerts, N. W., Huffman, J. C., Iyer, S. S., Pacold, M. and Phomphrai, K. (2000). "Molecular Design of Single-Site Metal Alkoxide Catalyst Precursors for Ring-Opening Polymerization Reactions Leading to Polyoxygenates. 1. Polylactide Formation by Achiral and Chiral Magnesium and Zinc Alkoxides, (.eta.3-L)MOR, Where L = Trispyrazolyl- and Trisindazolylborate Ligands." J. Am. Chem. Soc. 122(48): 11845-11854.
• Chisholm, M. H., Davidson, E. R., Huffman, J. C. and Quinlan, K. B. (2000). "Influence of alkoxide and thiolate ligands on the structure and reactivity of Molybdenum and Tungsten complexes." Abstr. Pap. - Am. Chem. Soc. 220th: INOR-512.
• Chisholm, M. H., Click, D. R. and Huffman, J. C. (2000). "Further Studies on the Substitutional Behavior of 1,2-Mo2Br2(CH2SiMe3)4. Alkyl, Amide, Phosphide, Alkoxide, and Thiolate for Bromide Exchange and Isomerizations of 1,1- and 1,2-Mo2X2(CH2SiMe3)4 Compounds." Organometallics 19(19): 3916-3924.
• Chisholm, M. H., Macintosh, A. M., Huffman, J. C., Wu, D., Davidson, E. R., Clark, R. J. H. and Firth, S. (2000). "Dimolybdenum Bis((S,S,S)-triisopropanolaminate(3-)): A Blue Compound with an Unusual Mo-Mo Triple Bond." Inorg. Chem. 39(16): 3544-3550.
• Chisholm, M. H., Huffman, J. C. and Iyer, S. S. (2000). "Some studies of the substitution chemistry of [Rh2(OAc)2(CH3CN)4][BF4]2 with monodentate and bidentate tertiary phosphines." Dalton(9): 1483-148.
• Chisholm, M. H., Folting, K., Huffman, J. C., Li, H., Macintosh, A. M. and Wu, D.-D. (2000). "d3-d3 diolates of dimolybdenum and ditungsten. Part 4. Molybdenum derivatives of S(-)-1,1-diphenyl-1,2-propanediol, S(-)-1,1,2-triphenyl-1,2-ethanediol and (1R, 2R)-(-)-1,2-dicyclohexyl-1,2-ethanediol." Polyhedron 19(4): 375-380.
• Coalter, J. N., III, Huffman, J. C. and Caulton, K. G. (2000). "Ruthenium carbenes derived from cyclic ethers and amines." Abstr. Pap. - Am. Chem. Soc. 220th: INOR-526.
• Coalter, J. N., III, Huffman, J. C. and Caulton, K. G. (2000). "Facile X-C(sp2) bond cleavage (X = H, R, OR, NR2) by .pi.-acid abstraction from aldehydes, esters, amides, amines, and imines." Abstr. Pap. - Am. Chem. Soc. 220th: INOR-210.
• Coalter, J. N., III, Huffman, J. C. and Caulton, K. G. (2000). "Cleavage of H-C(sp2) and C(sp2)-X Bonds (X = Alkyl, Aryl, OR, NR2): Facile Decarbonylation, Isonitrile Abstraction, or Dehydrogenation of Aldehydes, Esters, Amides, Amines, and Imines by [RuHCl(PiPr3)2]2." Organometallics 19(18): 3569-3578.
• Coalter, J. N., III, Huffman, J. C., Streib, W. E. and Caulton, K. G. (2000). "A New Class of Electron-Rich Unsaturated Molecules: Ru2HnX4-n(PiPr3)4, X = Anion." Inorg. Chem. 39(17): 3757-3764.
• Coalter, J. N., III, Bollinger, J. C., Huffman, J. C., Werner-Zwanziger, U., Caulton, K. G., Davidson, E. R., Gerard, H., Clot, E. and Eisenstein, O. (2000). "Coordinated carbenes from electron-rich olefins on RuHCl(PPri3)2." New J. Chem. 24(1): 9-26.
• Gashti, A. N., Huffman, J. C., Edwards, A., Szekeley, G., Siedle, A. R., Karty, J. A., Reilly, J. P. and Todd, L. J. (2000). "Fluorination studies of the [commo-3,3'-Co(3,1,2-CoC2B9H11)2-1] ion." J. Organomet. Chem. 614-615: 120-124.
• Gemel, C., Huffman, J. C., Caulton, K. G., Mauthner, K. and Kirchner, K. (2000). "Solution and solid-gas reactivity of unsaturated [RuCp(tmeda)]+ (tmeda = Me2NC2H4NMe2)." J. Organomet. Chem. 593-594: 342-353.
• Gottschalk-Gaudig, T., Huffman, J. C., Gerard, H., Eisenstein, O. and Caulton, K. G. (2000). "Unsaturated Ru(0) Species with a Constrained Bis-Phosphine Ligand: [Ru(CO)2(tBu2PCH2CH2PtBu2)]2. Comparison to [Ru(CO)2(PtBu2Me)2]." Inorg. Chem. 39(18): 3957-3962.
• Seddon, E. J., Huffman, J. C. and Christou, G. (2000). "A new core topology in hexanuclear iron(III) carboxylate chemistry: [Fe6O3(O2CMe)9(OEt)2(bpy)2](ClO4)." Dalton(23): 4446-4452.
• Seddon, E. J., Yoo, J., Folting, K., Huffman, J. C., Hendrickson, D. N. and Christou, G. (2000). "Dinuclear and hexanuclear iron(III) carboxylate clusters with a bis(bipyridine) ligand: supramolecular aggregation of [Fe2O2] units to give a [Fe6O6] ladder structure." Dalton(20): 3640-3648.
• Wang, S., Wemple, M. S., Yoo, J., Folting, K., Huffman, J. C., Hagen, K. S., Hendrickson, D. N. and Christou, G. (2000). "Tetranuclear Manganese Carboxylate Complexes with a Trigonal Pyramidal Metal Topology via Controlled Potential Electrolysis." Inorg. Chem. 39(7): 1501-1513.
• Yandulov, D. V., Huffman, J. C. and Caulton, K. G. (2000). "An osmium hydrido methyl species via an unconventional methyl transfer." New J. Chem. 24(9): 649-650.
• Yandulov, D. V., Huang, D., Huffman, J. C. and Caulton, K. G. (2000). "Structural Distortions in mer-M(H)3(NO)L2 (M = Ru, Os) and Their Influence on Intramolecular Fluxionality and Quantum Exchange Coupling." Inorg. Chem. 39(9): 1919-1932.