Chemistry | Charactrzn of Paramagnetic Mol
C639 | 22931 | Lee

C639 Characterization of Paramagnetic Molecules (3 cr.) Definitions
of diamagnetism, paramagnetism, magnetization and magnetic
susceptibility; the Curie Law; orbital angular momentum; the Van
Vleck equation; zero-field splitting; exchange interactions in
dinuclear and polynuclear metal clusters. Basic concepts of
paramagnetic NMR; spin delocalization mechanisms and isotropic
shifts; contact and dipolar contributions. EPR of transition
complexes; g-value anisotropy as a function of coordination geometry.