C561:
Atomic and Molecular Quantum Theory
Instructor: Srinivasan S. Iyengar
email: iyengar@indiana.edu
Instructor's Messages for students:
Welcome to C561
Instructor Officer hrs: Monday 1:30-3PM, Thursday 2:30-3:30PM (Chemistry C202B)
AI: Sowmya Ghosh. Office hours: TBA
Homeworks are in the notes. You should read the notes carefully to make sure
you do not miss the homeworks. These are due every week, on Wednessdays.
Part I: Fundamental concepts
- Course Outline
- Handout: Linear algebra
Experimental considerations that provide a rationalization for
the postulates of quantum mechanics.
- The Stern-Gerlach Experiments
To test the Stern-Gerlach experiments, download
this nifty java
applet. It will allow you to run the Stern-Gerlach experiments on your
computer and understand it better. (You will need to have Java
installed and enabled for this to run from the browser.) Click on the
help menu to customize experiments.
- The Stern-Gerlach experiments
explained using plane polarized light and circularly polarized
light
- A brief summary of Stern-Gerlach experiments
- de Broglie's Wave particle duality
Formal considerations that rationalize the Stern-Gerlach
experiments and eventually lead us to the postulates of
quantum mechanics.
- Representation theory, Dirac notations, Hilbert space
- Introduction to operators, Discrete and continuous
representations, Coordinate and momentum representation, the quantum-mechanical Wavefunction
The following additional material is related to what we have learned
thus far. Hence please go over these yourself. We will cover it later
in class, quickly. If you have trouble see me. You are responsible
for the homework problems in these sections.
Simultaneous additional reading: Important Summary of Dirac notation
Simultaneous additional reading: Theory of Operators: I
Simultaneous additional reading: Pauli Spin matrices
Simultaneous additional reading: Change of basis
Simultaneous additional reading:
The Concept of Measurement in quantum mechanics
- Postulates of Quantum mechanics
Homework: Justify the stated postulates through your knowledge of the Stern-Gerlach experiments.
The statement on "uncertainty" is really a result of the vector
spaces idea that we have discussed above.
- Simultaneous observables, Commutation relations, expectation values
- Uncertainty Principle and Coherent states
The Schrodinger Equation and associated properties.
- The Time dependent Schrodinger Equation
Simultaneous additional reading:
Solving the time-dependent Schrodinger Equation.
Simultaneous additional reading:
The Classical limit and the WKB theory
Simultaneous additional reading:
Probability Current and the continuity equation.
Simultaneous additional reading:
Dirac quantization, The Schrodinger picture and the Heisenberg
Picture, Heisenberg's equation of motion
(The Heisenberg's equation of motion is analogous to the
time-dependent Schrodinger Equation, but as we see here
provides connections to classical mechanics as well)
At this point you may wish to read a little about the
history of quantum mechanics . The link above oulines some
of the struggles between Schrodinger and Heisenberg in arriving
at a unifying picture of quantum mechanics. It is Dirac's path
that we have chosen in this class, which does unify the two
pictures. In addition, through the set of readings provided
here, you may see that the connections to classical mechanics
can be quite exciting.
- The Time independent Schrodinger Equation.
Simultaneous additional reading: Theory of Operators: II. Hermitian operators and their properties.
Part II: Analytically solvable model problems for free-particle
- Particle-in-a-box